Ductilizing Mo alloys via nanoparticle-stabilized microstructural hierarchy

Stress-induced Transformations in Ti-mo Alloys

Optimizaton of Mo-Si-B Intermetallic Alloys

Mo-Si-B intermetallics consisting of the phases Mo3Si and Mo5SiB2, and a molybdenum solid solution (“ -Mo”), have melting points on the order of 2000 °C. These alloys have potential as oxidationresistant ultra-high-temperature structural materials. They can be designed with microstructures containing either individual -Mo particles or a continuous -Mo phase. A compilation of existing data shows...

Misfit stabilized embedded nanoparticles in metallic alloys.

Nanoscale inhomogeneities are typical for numerous metallic alloys and crucially important for their practical applications. At the same time, stabilization mechanisms of such a state are poorly understood. We present a general overview of the problem, together with a more detailed discussion of the prototype example, namely, Guinier-Preston zones in Al-based alloys. It is shown that coherent s...

Interfacial Molecular Imprinting in Nanoparticle-Stabilized Emulsions

A new interfacial nano and molecular imprinting approach is developed to prepare spherical molecularly imprinted polymers with well-controlled hierarchical structures. This method is based on Pickering emulsion polymerization using template-modified colloidal particles. The interfacial imprinting is carried out in particle-stabilized oil-in-water emulsions, where the molecular template is prese...

Ammonia synthesis over Co-Mo alloy nanoparticle catalyst prepared via sodium naphthalenide-driven reduction.

We report the synthesis of Co-Mo alloy nanoparticles with a uniform distribution of the alloy elements on CeO2via sodium naphthalenide-driven reduction. The resulting sample functions as a highly efficient and stable catalyst for ammonia synthesis. Based on the metal weight, the catalytic activity is ca. 20 times higher than that of Co3Mo3N.